Ru (dpp) 3 (PF6) 2

Ru (dpp) 3 (PF6) 2 is a complex containing metallic ruthenium (Ru) and is a chemiluminescent oxygen probe. [Ru (dpp) 3]2+ is a luminescent substance that can undergo metal-to-ligand charge transfer (MLCT), and fluorescence will appear during the transfer of Ru to the ligand. At the same time, the fluorescence of Ru (dpp) 3 (PF6) 2 is effectively quenched by molecular oxygen, so it is widely used in biosensors, environmental monitoring, and materials science. The property of Ru (dpp) 3 (PF6) 2, which oxidizes Ru2+ to Ru3+, has also been used to design and construct solid-state light-emitting electrochemical cells[1][2][3].

Product Specifications

CAS Number

[123148-15-2]

UNSPSC

12352200

Hazard Statement

H315, H319

Target

Fluorescent Dye

Type

Biochemical Assay Reagents

Related Pathways

Others

Field of Research

Others

Assay Protocol

https://www.medchemexpress.com/ru-dpp-3-pf6-2.html

Purity

98.20

Solubility

DMSO : ≥ 100 mg/mL

Smiles

F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[N]12=CC=C(C3=CC=CC=C3)C(C=C4)=C1C5=C4C(C6=CC=CC=C6)=CC=[N]5[Ru+2]278([N]9=CC=C(C%10=CC=CC=C%10)C(C=C%11)=C9C%12=C%11C(C%13=CC=CC=C%13)=CC=[N]8%12)[N]%14=CC=C(C%15=CC=CC=C%15)C(C=C%16)=C%14C%17=C%16C(C%18=CC=CC=C%18)=CC=[N]7%17

Molecular Formula

C72H48F12N6P2Ru

Molecular Weight

1388.19

Precautions

H315, H319

References & Citations

[1]Kozlov D V, et al. Photochemically reversible luminescence lifetime switching in metal− organic systems[J]. The Journal of Physical Chemistry A, 2004, 108 (48) : 10619-10622.|[2]Barbante G J, et al. Solid state spectroelectrochemistry of microparticles of ruthenium diimine complexes immobilised on optically transparent electrodes[J]. Journal of Solid State Electrochemistry, 2009, 13: 599-608.|[3]Sun J, et al. Visible-light harvesting iridium complexes as singlet oxygen sensitizers for photooxidation of 1,5-dihydroxynaphthalene. Chem Commun (Camb) . 2012 May 4;48 (35) :4169-71.