Tylosin A Aldol

7-Oxabicyclo[13.2.1]octadeca-10,12-diene-6,14-dione, 9-[[(6-deoxy-2,3-di-O-methyl-β-D-allopyranosyl)oxy]methyl]-2-[[3,6-dideoxy-4-O-(2,6-dideoxy-3-C-methyl-α-L-ribo-hexopyranosyl)-3-(dimethylamino)-β-D-glucopyranosyl]oxy]-8-ethyl-4,16-dihydroxy-3,11,15-trimethyl-, (1R,2S,3S,4R,8R,9R,10E,12E,15S,16R)-; 7-Oxabicyclo[13.2.1]octadeca-10,12-diene-6,14-dione, 9-[[(6-deoxy-2,3-di-O-methyl-β-D-allopyranosyl)oxy]methyl]-2-[[3,6-dideoxy-4-O-(2,6-dideoxy-3-C-methyl-α-L-ribo-hexopyranosyl)-3-(dimethylamino)-β-D-glucopyranosyl]oxy]-8-ethyl-4,16-dihydroxy-3,11,15-trimethyl-, [1R-(1R*,2S*,3S*,4R*,8R*,9R*,10E,12E,15S*,16R*)]- (9CI); (1R,2S,3S,4R,8R,9R,10E,12E,15S,16R)-9-[[(6-Deoxy-2,3-di-O-methyl-β-D-allopyranosyl)oxy]methyl]-2-[[3,6-dideoxy-4-O-(2,6-dideoxy-3-C-methyl-α-L-ribo-hexopyranosyl)-3-(dimethylamino)-β-D-glucopyranosyl]oxy]-8-ethyl-4,16-dihydroxy-3,11,15-trimethyl-7-oxabicyclo[13.2.1]octadeca-10,12-diene-6,14-dione

CC[C@H]1OC(=O)C[C@@H](O)[C@H](C)[C@@H](O[C@@H]2O[C@H](C)[C@@H](O[C@H]3C[C@@](C)(O)[C@@H](O)[C@H](C)O3)[C@@H]([C@H]2O)N(C)C)[C@H]4C[C@@H](O)[C@](C)(C4)C(=O)\C=C\C(=C\[C@@H]1CO[C@@H]5O[C@H](C)[C@@H](O)[C@@H](OC)[C@H]5OC)\C

InChI=1S/C46H77NO17/c1-13-30-28(21-58-44-41(57-12)40(56-11)36(52)24(4)60-44)16-22(2)14-15-31(49)45(7)19-27(17-32(45)50)38(23(3)29(48)18-33(51)62-30)64-43-37(53)35(47(9)10)39(25(5)61-43)63-34-20-46(8,55)42(54)26(6)59-34/h14-16,23-30,32,34-44,48,50,52-55H,13,17-21H2,1-12H3/b15-14+,22-16+/t23-,24+,25+,26-,27-,28+,29+,30+,32+,34-,35+,36+,37+,38+,39+,40+,41+,42-,43-,44+,45+,46+/m0/s1

IUPAC name: (1R,2S,3S,4R,8R,9R,10E,12E,15S,16R)-2-[(2R,3R,4R,5S,6R)-5-[(2S,4R,5S,6S)-4,5-dihydroxy-4,6-dimethyloxan-2-yl]oxy-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-8-ethyl-4,16-dihydroxy-9-[[(2R,3R,4R,5R,6R)-5-hydroxy-3,4-dimethoxy-6-methyloxan-2-yl]oxymethyl]-3,11,15-trimethyl-7-oxabicyclo[13.2.1]octadeca-10,12-diene-6,14-dione