Carfilzomib Impurity 102

2- ((4S,7S,10S,13S) -10-benzyl-7-isobutyl-15-methyl-1-morpholino-2,5,8,11-tetraoxo-4-phenethyl-3,6,9,12-tetraazahexadecan-13-yl) -2,3-dihydroxy-3-methyl-1- (((S) -1- (((S) -4-methyl-1- (((S) -1- (((S) -4-methyl-1- ((R) -2-methyloxiran-2-yl) -1-oxopentan-2-yl) amino) -1-oxo-3-phenylpropan-2-yl) amino) -1-oxopentan-2-yl) amino) -1-oxo-4-phenylbutan-2-yl) carbamoyl) -8-oxa-5-azaspiro[4.5]decan-5-ium chloride and 4- ((4S,7S,10S,13S) -10-benzyl-15-hydroxy-7,13-diisobutyl-15-methyl-1-morpholino-2,5,8,11,14-pentaoxo-4-phenethyl-3,6,9,12-tetraazahexadecan-16-yl) -4- ((4S,7S,10S,13S) -10-benzyl-7-isobutyl-15-methyl-13- ((R) -2-methyloxirane-2-carbonyl) -2,5,8,11-tetraoxo-4-phenethyl-3,6,9,12-tetraazahexadecyl) morpholin-4-ium chloride