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Tris (4,7-diphenyl-1,10-phenanthroline) ruthenium (II) dichloride

Tris (4,7-diphenyl-1,10-phenanthroline) ruthenium (II) dichloride ([Ru (dpp) 3]2+) is an electrochemiluminescent (ECL) probe that can be used to modify the electrode surface to detect sulfate (S2O82-) and oxalate. Tris (4,7-diphenyl-1,10-phenanthroline) ruthenium (II) dichloride can generate excited state species based on electrochemical reactions and release photons through irreversible redox reactions. When used as a cathode to detect persulfate, it can avoid the interference of hydrogen evolution. At the same time, the anode shows a wide linear range for oxalate. Tris (4,7-diphenyl-1,10-phenanthroline) ruthenium (II) dichloride can be used to construct a regenerable ECL sensor[1][2][3].

Product Specifications

CAS Number

36309-88-3

UNSPSC

12171500

Hazard Statement

H302, H315, H319, H335

Target

Fluorescent Dye

Type

Dye Reagents

Related Pathways

Others

Field of Research

Others

Assay Protocol

https://www.medchemexpress.com/tris-4-7-diphenyl-1-10-phenanthroline-ruthenium-ii-dichloride.html

Purity

99.78

Solubility

DMSO : 25 mg/mL (ultrasonic) |Ethanol : 8.33 mg/mL (ultrasonic; warming; heat to 60°C)

Smiles

C1(C=C2)=C(C3=C2C(C4=CC=CC=C4)=CC=[N]3[Ru+2]567([N]8=CC=C(C9=CC=CC=C9)C%10=C8C%11=[N]7C=CC(C%12=CC=CC=C%12)=C%11C=C%10)[N]%13=CC=C(C%14=CC=CC=C%14)C%15=C%13C%16=[N]6C=CC(C%17=CC=CC=C%17)=C%16C=C%15)[N]5=CC=C1C%18=CC=CC=C%18.[2Cl-]

Molecular Formula

C72H48Cl2N6Ru

Molecular Weight

1169.17

Precautions

H302, H315, H319, H335

References & Citations

[1]Hao Xu, et al. A real-time ratiometric method for the determination of molecular oxygen inside living cells using sol-gel-based spherical optical nanosensors with applications to rat C6 glioma. Anal Chem. 2001 Sep 1;73 (17) :4124-33.|[2]Hałasa R, et al. Application of tris- (4,7-Diphenyl-1,10 phenanthroline) ruthenium (II) Dichloride to Detection of Microorganisms in Pharmaceutical Products. Pharmaceuticals (Basel) . 2023 Jun 8;16 (6) :856.|[3]Hanif S, et al. Regenerable sensor based on tris (4,7'-diphenyl-1,10-phenanthroline) ruthenium (II) for anodic and cathodic electrochemiluminescence applications. Bioelectrochemistry. 2023 Feb;149:108313.

Shipping Conditions

Room Temperature

Storage Conditions

4°C (Powder, protect from light, stored under nitrogen)

Scientific Category

Dye Reagents

Clinical Information

No Development Reported

Available Sizes

Frequently Asked Questions

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